Corrosion behavior and surface characterization of Ti-20Cr alloy in a solution containing fluoride.

نویسندگان

  • Shinji Takemoto
  • Masayuki Hattori
  • Masao Yoshinari
  • Eiji Kawada
  • Katsuhiko Asami
  • Yutaka Oda
چکیده

The purpose of this study was to investigate the correlation between corrosion resistance and surface composition of an experimental Ti-20 mass% Cr casting alloy in a saline solution containing fluoride. The alloy had a greater resistance to corrosion in a fluoride-containing saline solution than did commercially pure titanium. However, with confirmed dissolution of titanium and chromium, it meant that the fluoride in the saline solution corroded the alloy slightly. X-ray photoelectron spectroscopy analysis revealed that the surface composition of the alloy consisted of titanium and chromium oxides containing hydroxide. The [Ti]/([Ti] + [Cr]) ratio in the surface oxide film decreased when immersed in fluoride-containing saline solution, that is, the surface oxide film became chromium-rich oxide. Therefore, the alloy obtained good corrosion resistance to fluoride due to formation of a chromium-rich oxide film.

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عنوان ژورنال:
  • Dental materials journal

دوره 23 3  شماره 

صفحات  -

تاریخ انتشار 2004